Characterization of a PEDOT:PSS Electrolytic Device Using an in situ Spectroelectrochemical Technique
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PEDOT:PSS, a conjugated polymer, has demonstrated great potential in emerging applications due to its variable conductivity and spectral attenuation. However, it is necessary to understand the relationship between these properties and the doping state of PEDOT:PSS. This work uses an in situ spectroelectrochemical experiment to measure conductance and spectral attenuation of PEDOT:PSS while being dedoped quasi-statically with lithium ions. Results show a reversible decrease in conductivity during dedoping with a maximum on/off ratio of 2500. The relationship between conductivity and doping state displays a sigmoidal shape with minimum conductivity at ~1.2mC of intercalated charge. Migration speed of lithium through PEDOT:PSS was found to have a power-law speed-time relationship, where the exponent was on average 0.715 for applied voltages of 2V-5V. This work provides important parameters to facilitate simulation of complex PEDOT:PSS polymer-electrolyte devices.
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Copyright © 2013 the author(s). Theses may be used for non-commercial research, educational, or related academic purposes only. Such uses include personal study, research, scholarship, and teaching. Theses may only be shared by linking to Carleton University Institutional Repository and no part may be used without proper attribution to the author. No part may be used for commercial purposes directly or indirectly via a for-profit platform; no adaptation or derivative works are permitted without consent from the copyright owner.
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- 2013
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barreraramirez-characterizationofapedotpsselectrolyticdevice.pdf | 2023-05-04 | Public | Download |